I would have to go with Jens Pulver and Takanori Gomi. They had a very good fight back in the Pride era and it was mostly boxing, no holds or takedowns. One of the best heavyweights in the boxing department was Andrei Arlovski although his chin has never been top notch and has gotten worse with time. Mark Hunt is another one with good chances due to his power and incredible chin.
I don't see any MMA fighter doing something in boxing, even Anderson Silva who has the better boxing technic and natural talent, loss by a random unkown guy brazilian in boxing.His record in pugilism is 1-1 or something like that.
If you can box, later or sooner you trie at boxing, because is where the glory and the purse is.
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