People keep asking this question on every boxing forum/blog so:
(Opponents not mentioned are "bums"):
D level opponents:
___________________
John Anderson Carvalho (Record 19W-3L-1D at the time):
__________________________________________________ ____
Beat Anderson Clayton.
D+ level opponents:
___________________
Malik Dziarra (Record 29W-3L-0D at the time):
____________________________________________
Beat Mahir Oral (Former WBC International middleweight title-holder).
Lost TKO 9 to Mario Veit for the IBF Inter-Continental super middleweight title.
C- level opponents:
___________________
(Past prime) Javier Alberto Mamani (Record 35W-7L-1D at the time):
__________________________________________________ ______
Beat Ariel Gabriel Chaves (Beat Carlos Manuel Baldomir X2).
Beat Crazy Kim (Beat Nobuhiro Ishida X2).
Beat Walter Javier Crucce (X2) (Beat a dude who beat Baldomir as well).
Beat Jose Joaquin Rosa Gomez (Beat Former WBA World lightweight champion Raul Horacio Balbi).
Beat Miguel Angel Arroyo.
C level opponents:
__________________
Makoto Fuchigami (Record 19W-6L-0D at the time):
________________________________________________
Former OPBF middleweight title-holder.
Beat Koji Sato (Former OPBF middleweight title-holder).
Beat Tetsuya Suzuki (Former OPBF middleweight title-holder).
Nilson Julio Tapia (Record 14W-2L-1D at the time):
__________________________________________
Beat Santiago Samaniego (Former interim WBA World light middleweight title-holder).
Beat Alfonso Mosquera (Also beat Santiago Samaniego).
Lost MD against Austin Trout (Former WBA World light middleweight champ).
Golovkin is the first to KO him.
Lajuan Simon (Rec 23W-3L-2D at the time):
_________________________________________
Beat Elvin Ayala (Draw against Sergio Mora).
Lost UD 12 against Arthur Abraham for the IBF middleweight title.
Lost UD 12 against Sebastian Sylvester for the IBF International middleweight title.
Beat Corey Johnson (Draw against Shannan Taylor).
Beat Darnell Boone (Bum yet he did beat Adonis Stevenson).
Golovkin is the first to KO him.
Mehdi Bouadla (Record 11W-1L-0D at the time. Record is 28W-5L-0D now:
__________________________________________________ ___________
Former IBF International super middleweight title-holder.
Former WBO Inter-Continental super middleweight title-holder.
Former WBA International middleweight title-holder.
Beat Morrade Hakkar (Former European middleweight champion).
Beat Michael Henrotin (Former IBF Inter-Continental super middleweight title-holder).
Beat Francisco Antonio Mora (Beat Ariel Gabriel Chaves X2).
Lost TKO 8 to Arthur Abraham for the WBO super middleweight title.
C+ level opponents:
___________________
(Past prime) Nobuhiro Ishida (Record 24W-8L-2D at the time):
__________________________________________________ __________
Former interim WBA World light middleweight title-holder.
Beat James Kirkland (first to defeat and to KO Kirkland).
Beat Javier Alberto Mamani (when it still mattered).
Golovkin is the first to KO him.
Ian Gardner (Record 20W-3L-0D at the time):
____________________________________________
Lost SD against Peter Manfredo Jr.
Beat Deandre Latimore (Beat Sechew Powell and SD loss to Cory Spinks for the IBF light middleweight title).
Beat Kuvanych Toygonbayev (Beat Oba Carr & Andrey Tsurkan).
Beat Tokunbo Olajide.
Beat Troy Rowland (Beat Charles Whittaker).
Beat Gilberto Reyes (Beat Carlos Gonzalez, former WBO light welterweight champion).
Lost UD 12 to Arthur Abraham for the WBA Inter-Continental middleweight title.
Lost TKO 11 to Chad Dawson (Former WBC & IBF light heavyweight champion).
B- level (past prime) Kassim Ouma (Record 27W-7L-1D at the time):
__________________________________________________ _______________
Former IBF light middleweight champion.
Beat Verno Phillips (X2) (Former IBF light middleweight champion).
Beat Marco Antonio Rubio (Beat Carlos Manuel Baldomir & David Lemieux).
Beat Sechew Powell (Beat Former IBF light middleweight champions Cornelius Bundrage & Ishe Smith).
Beat Alex Bunema (Beat Former IBF light welterweight champion Vince Phillips & IBF middleweight champ Roman Karmazin).
Beat Kuvanych Toygonbayev (Beat Oba Carr & Andrey Tsurkan).
Beat Kofi Jantuah (Beat Marco Antonio Rubio & Santiago Samaniego).
Beat Carlos Bojorquez (Beat Pernell Whitaker).
Beat Tony Marshall.
B level Grzegorz Proksa (Record 28W-1L-0D at the time):
__________________________________________________ ______
Former European middleweight champion.
The Ring's #10 Rated at the time.
Beat Sebastian Sylvester (Former IBF middleweight champion & European middleweight champion).
Beat Steve Conway (Former International Boxing Organization light middleweight champion).
Beat Pablo Navascues (Draw against Javier Castillejo).
B level Gabriel Rosado (Record 21W-5L-0D at the time):
__________________________________________________ ____
The Ring's #9 Rated at the time.
Beat Kassim Ouma (Former IBF light middleweight champion).
Beat Sechew Powell (Beat Former IBF light middleweight champions Cornelius Bundrage & Ishe Smith).
Beat Jesus Soto Karass (Beat former european welterweight champ Selcuk Aydin & former WBC/IBF welterweight champion Andre Berto).
Beat Charles Whittaker (IBF Light Middleweight rankings #2 Spot at the time).
Beat Saul Roman (Beat Marco Antonio Rubio, Kassim Ouma).
Lost TKO 10 to Peter Quillin (fight was an even 85-85, bad cut but Rosado could see no problem,
bad timing to stop the fight) (WBO middleweight champion).
B+ level Matthew Macklin (Record 29W-4L-0D at the time):
__________________________________________________ _______
Former European middleweight champion.
Should have won the WBA Super World middleweight title.
The Ring's #5 Rated at the time.
Beat Felix Sturm (robbed) (former WBO & WBA middleweight champion).
Beat Joachim Alcine (former WBA World light middleweight champion).
Beat Amin Asikainen (former European middleweight champion).
Beat Luis Ramon Campas (former IBF light middleweight champion).
Beat Wayne El****.
Lost KO 11 to Sergio Gabriel Martinez (knocked down Martinez in round 7).
Upcoming:
C+ level Curtis Stevens 25W-3L-0D:
______________________________
The Ring's #9 Rated.
Beat Piotr Wilczewski (former european super middleweight champion).
Beat Saul Roman (Beat Marco Antonio Rubio, Kassim Ouma).
Beat Elvin Ayala (Draw against Sergio Mora).
There you have it, mostly C level guys, a few B level guys.
It's a much more impressive resume than Peter Quillin's, on the other hand he really needs to step it up.
(Opponents not mentioned are "bums"):
D level opponents:
___________________
John Anderson Carvalho (Record 19W-3L-1D at the time):
__________________________________________________ ____
Beat Anderson Clayton.
D+ level opponents:
___________________
Malik Dziarra (Record 29W-3L-0D at the time):
____________________________________________
Beat Mahir Oral (Former WBC International middleweight title-holder).
Lost TKO 9 to Mario Veit for the IBF Inter-Continental super middleweight title.
C- level opponents:
___________________
(Past prime) Javier Alberto Mamani (Record 35W-7L-1D at the time):
__________________________________________________ ______
Beat Ariel Gabriel Chaves (Beat Carlos Manuel Baldomir X2).
Beat Crazy Kim (Beat Nobuhiro Ishida X2).
Beat Walter Javier Crucce (X2) (Beat a dude who beat Baldomir as well).
Beat Jose Joaquin Rosa Gomez (Beat Former WBA World lightweight champion Raul Horacio Balbi).
Beat Miguel Angel Arroyo.
C level opponents:
__________________
Makoto Fuchigami (Record 19W-6L-0D at the time):
________________________________________________
Former OPBF middleweight title-holder.
Beat Koji Sato (Former OPBF middleweight title-holder).
Beat Tetsuya Suzuki (Former OPBF middleweight title-holder).
Nilson Julio Tapia (Record 14W-2L-1D at the time):
__________________________________________
Beat Santiago Samaniego (Former interim WBA World light middleweight title-holder).
Beat Alfonso Mosquera (Also beat Santiago Samaniego).
Lost MD against Austin Trout (Former WBA World light middleweight champ).
Golovkin is the first to KO him.
Lajuan Simon (Rec 23W-3L-2D at the time):
_________________________________________
Beat Elvin Ayala (Draw against Sergio Mora).
Lost UD 12 against Arthur Abraham for the IBF middleweight title.
Lost UD 12 against Sebastian Sylvester for the IBF International middleweight title.
Beat Corey Johnson (Draw against Shannan Taylor).
Beat Darnell Boone (Bum yet he did beat Adonis Stevenson).
Golovkin is the first to KO him.
Mehdi Bouadla (Record 11W-1L-0D at the time. Record is 28W-5L-0D now:
__________________________________________________ ___________
Former IBF International super middleweight title-holder.
Former WBO Inter-Continental super middleweight title-holder.
Former WBA International middleweight title-holder.
Beat Morrade Hakkar (Former European middleweight champion).
Beat Michael Henrotin (Former IBF Inter-Continental super middleweight title-holder).
Beat Francisco Antonio Mora (Beat Ariel Gabriel Chaves X2).
Lost TKO 8 to Arthur Abraham for the WBO super middleweight title.
C+ level opponents:
___________________
(Past prime) Nobuhiro Ishida (Record 24W-8L-2D at the time):
__________________________________________________ __________
Former interim WBA World light middleweight title-holder.
Beat James Kirkland (first to defeat and to KO Kirkland).
Beat Javier Alberto Mamani (when it still mattered).
Golovkin is the first to KO him.
Ian Gardner (Record 20W-3L-0D at the time):
____________________________________________
Lost SD against Peter Manfredo Jr.
Beat Deandre Latimore (Beat Sechew Powell and SD loss to Cory Spinks for the IBF light middleweight title).
Beat Kuvanych Toygonbayev (Beat Oba Carr & Andrey Tsurkan).
Beat Tokunbo Olajide.
Beat Troy Rowland (Beat Charles Whittaker).
Beat Gilberto Reyes (Beat Carlos Gonzalez, former WBO light welterweight champion).
Lost UD 12 to Arthur Abraham for the WBA Inter-Continental middleweight title.
Lost TKO 11 to Chad Dawson (Former WBC & IBF light heavyweight champion).
B- level (past prime) Kassim Ouma (Record 27W-7L-1D at the time):
__________________________________________________ _______________
Former IBF light middleweight champion.
Beat Verno Phillips (X2) (Former IBF light middleweight champion).
Beat Marco Antonio Rubio (Beat Carlos Manuel Baldomir & David Lemieux).
Beat Sechew Powell (Beat Former IBF light middleweight champions Cornelius Bundrage & Ishe Smith).
Beat Alex Bunema (Beat Former IBF light welterweight champion Vince Phillips & IBF middleweight champ Roman Karmazin).
Beat Kuvanych Toygonbayev (Beat Oba Carr & Andrey Tsurkan).
Beat Kofi Jantuah (Beat Marco Antonio Rubio & Santiago Samaniego).
Beat Carlos Bojorquez (Beat Pernell Whitaker).
Beat Tony Marshall.
B level Grzegorz Proksa (Record 28W-1L-0D at the time):
__________________________________________________ ______
Former European middleweight champion.
The Ring's #10 Rated at the time.
Beat Sebastian Sylvester (Former IBF middleweight champion & European middleweight champion).
Beat Steve Conway (Former International Boxing Organization light middleweight champion).
Beat Pablo Navascues (Draw against Javier Castillejo).
B level Gabriel Rosado (Record 21W-5L-0D at the time):
__________________________________________________ ____
The Ring's #9 Rated at the time.
Beat Kassim Ouma (Former IBF light middleweight champion).
Beat Sechew Powell (Beat Former IBF light middleweight champions Cornelius Bundrage & Ishe Smith).
Beat Jesus Soto Karass (Beat former european welterweight champ Selcuk Aydin & former WBC/IBF welterweight champion Andre Berto).
Beat Charles Whittaker (IBF Light Middleweight rankings #2 Spot at the time).
Beat Saul Roman (Beat Marco Antonio Rubio, Kassim Ouma).
Lost TKO 10 to Peter Quillin (fight was an even 85-85, bad cut but Rosado could see no problem,
bad timing to stop the fight) (WBO middleweight champion).
B+ level Matthew Macklin (Record 29W-4L-0D at the time):
__________________________________________________ _______
Former European middleweight champion.
Should have won the WBA Super World middleweight title.
The Ring's #5 Rated at the time.
Beat Felix Sturm (robbed) (former WBO & WBA middleweight champion).
Beat Joachim Alcine (former WBA World light middleweight champion).
Beat Amin Asikainen (former European middleweight champion).
Beat Luis Ramon Campas (former IBF light middleweight champion).
Beat Wayne El****.
Lost KO 11 to Sergio Gabriel Martinez (knocked down Martinez in round 7).
Upcoming:
C+ level Curtis Stevens 25W-3L-0D:
______________________________
The Ring's #9 Rated.
Beat Piotr Wilczewski (former european super middleweight champion).
Beat Saul Roman (Beat Marco Antonio Rubio, Kassim Ouma).
Beat Elvin Ayala (Draw against Sergio Mora).
There you have it, mostly C level guys, a few B level guys.
It's a much more impressive resume than Peter Quillin's, on the other hand he really needs to step it up.

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