I would say Donaire Mares because that is the bigger fight and the winner is on to fairly big things in the low weight classes.
Martinez-Golovkin is a very nice fight also, but I doubt it makes the winner a bankable star.
Based on purely which is the better fight without thinking about where it leads, I couldn't pick they should both be top-shelf contests. I could see Donaire eating up Mares but by the same token I could see Golovkin smashing Martinez but I think the guys involved are all close enough to at least make it a quality fight before such a scenario really took hold.
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